By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the previous decade, a lot study attempt has been dedicated to the layout and synthesis of recent reagents and catalysts which could impression carbon-hydrogen bond activation, more often than not due to the prospect that C−H activation may permit the conversion of inexpensive and considerable alkanes into invaluable functionalized natural compounds.
Alkane C-H Activation by way of Single-Site steel Catalysis offers the present cutting-edge improvement within the catalytic platforms for the catalytic trans-formations of alkanes below homogeneous stipulations. bankruptcy 1 bargains a complete precis of the most discoveries learned to date. bankruptcy 2 experiences the so-called electrophilic activation, initiated through Shulpín within the overdue 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, found via Hartwig, while bankruptcy four offers an up to date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of large curiosity with bioinorganic im-plications, and eventually bankruptcy 6 provides the functionalization of alkane C-H bonds by means of carbene or nitrene insertion.
The heritage of C-H bond activation, and the present study defined during this publication, spotlight the present learn and current the reader with an outlook of this box which is still explored through an more and more visionary and enthusiastic workforce of natural, organometallic, organic and actual chemists.
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